Pseudowollastonite

pseudowollastonite

breyite

davemaoite

wollastonite

Images

Formula: CaSiO3
Cyclosilicate (ring silicate), monoclinic paramorph of triclinic breyite, isometric davemaoite and triclinic wollastonite
Crystal System: Monoclinic
Luminescence: Lilac cathodoluminescence has been reported (Mindat)
Environments

Metamorphic environments
Hydrothermal environments

Pseudowollastonite is well known as an artificial high-temperature phase dimorphous with wollastonite from slags and cement, but also very rarely found in nature from pyrometamorphosed calcareous rocks. The structure contains isolated trisilicate rings (Si3O9)6- (Mindat).

Localities

At the Gurim anticline, Hatrurim Basin, Tamar Regional Council, Southern District, Israel, two new barium-bearing minerals, gurimite and hexacelsian, were discovered in veins of paralava cutting gehlenite - flamite hornfels. Gurimite and hexacelsian occur in inclusions in paralava and are associated with gehlenite, pseudowollastonite or wollastonite, rankinite, flamite, larnite, schorlomite, andradite, fluorapatite, fluorellestadite, kalsilite, cuspidine, aradite, zadovite and khesinite (MM 81.4.1009–1019).

At the Nabi Musafossil mud volcano, Jericho Governorate, West Bank, Palestine, pseudowollastonite, an extremely rare constituent of ultra high-temperature combustion metamorphic and igneous rocks, has been found as a rock-forming mineral in calcium-rich paralava veins. Pseudowollastonite-bearing paralavas are the products of combustion metamorphism associated with spontaneous burning of methane. The melt began to crystallise at 1480 to 1500°C about the ambient pressure. Pseudowollastonite enters two mineral assemblages:
(1) rankinite, larnite, nagelschmidtite, wollastonite, gehlenite-rich melilite, titanium-rich andradite, cuspidine and fluorapatite.
(2) parawollastonite, wollastonite, gehlenite-rich melilite, titanium-rich andradite and fluorellestadite.
It is argued that pseudowollastonite is so scarce in nature because its formation requires joint action of several uncommon factors: availability of hot melts of T > 1200°C that bear free calcium but are poor in magnesium and iron (mostly as Fe3+) and their crystallisation in the shallow crust followed by quenching (Lithos Volumes 134–135, Pages 75-90).

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