Calciolangbeinite

calciolangbeinite

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Formula: K2Ca2(SO4)3
Sulphate, langbeinite group, forms a solid solution series with langbeinite
Crystal System: Isometric
Specific gravity: 2.68 measured, 2.74 calculated
Hardness: 3 to 3½
Streak: White
Colour: Colourless
Luminescence: Not fluorescent under UV
Environments

Metamorphic environments
Fumeroles

Localities

At Har Parsa, Hatrurim Basin, Tamar Regional Council, Southern District, Israel, calciolangbeinite has been found in pyrometamorphic gehlenite-bearing rocks (EJM 28, 93-103).

At the type locality, the Yadovitaya fumarole, Second scoria cone, Northern Breakthrough, Great Fissure eruption, Tolbachik volcano, Kamchatka Krai, Russia, calciolangbeinite occurs in sublimates associated with langbeinite, piypite, hematite, rutile, pseudobrookite, orthoclase, lyonsite, lammerite, cyanochroite and chlorothionite. Calciolangbeinite occurs as tetrahedral to pseudo-octahedral crystals, and as anhedral grains up to 1 mm in size, aggregated into clusters up to 2 mm across, and forming crusts covering areas of up to 1.5 × 1.5 cm2 on the surface of volcanic scoria. Late-stage calciolangbeinite occurs in complex epitaxial intergrowths with langbeinite.
Calciolangbeinite is transparent and colourless with a white streak and vitreous lustre (MM 76.3.673–682).
Calciolangbeinite-O is the low-temperature, orthorhombic, paramorph and calciolangbeinite-C is the high-temperature, cubic paramorph. In both high-temperature fumaroles and pyrometamorphic rocks calciolangbeinite crystallises in the cubic modification, and during cooling its chemical variety close to the end-member composition undergoes phase transition to calciolangbeinite-O, whereas the magnesium-enriched varieties remain calciolangbeinite-C (MM 86.4.557-569).

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