Pavlovskyite

pavlovskyite

calcio-olivine

galuskinite

dellaite

Images

Formula: Ca8(SiO4)2(Si3O10)
Sorosilicate (Si2O7 groups)
Crystal system: Orthorhombic
Specific gravity: 2.97 measured, 2.997 calculated
Hardness: 6 to 6½
Streak: White
Colour: White
Luminescence: Not fluorescent under UV
Environments

Metamorphic environments

Localities

There are two co-type localities, the Birkhin gabbro massif, Narin-Kunta, Irkutsk Oblast, Russia and Xenolith no. 1, Lakargi Mountain, Upper Chegem volcanic caldera, Chegemsky District, Kabardino-Balkaria, Russia.
Pavlovskyite from both localities has the same composition and physical properties. It is colourless in thin section. In hand specimens it is white with a white streak and transparent with vitreous lustre (AM 97.4.503-512).

At the Birkhin gabbro massif, Narin-Kunta, Irkutsk Oblast, Russia, pavlovskyite was detected in altered silicate-carbonate xenoliths a few meters across. The pavlovskyite forms in symmetric veins cutting calcio-olivine skarn. The central part of these veins is composed of galuskinite and its low-temperature alteration products. Selvages consist of sub-parallel aggregates of fibrous pavlovskyite crystals, up to 0.3–0.4 mm in length, 10–30 µm thick, nucleating at the vein walls, and dellaite, filling space between pavlovskyite crystals and separating them from calcio-olivine. Occasionally, galuskinite veins are partially replaced by spurrite, or vice versa, and have a margin composed of pavlovskyite spherolites growing into calcio-olivine. Rare amoeba-like, highly-fractured grains of pavlovskyite up to 2 mm in size occur in calcio-olivine. The following minerals are noted in Birkhin skarns: calcio-olivine, galuskinite, larnite, bredigite, merwinite, monticellite, spurrite, kilchoanite, dellaite, cuspidine, hydroxylellestadite, spinel, magnetite, members of the gehlenite-åkermanite series, garnet of the grossular - andradite - schorlomite - kerimasite series, baghdadite, chlorbartonite, pyrrhotite, clintonite, fluorapatite, hydroxylapatite, hillebrandite, perovskite, wollastonite and vesuvianite.
The development of retrograde monticellite-dellaite intergrowths is characteristic of merwinite-gehlenite high-temperature skarns at Birkhin. In retrograde kilchoanite skarns containing merwinite and gehlenite, pavlovskyite and monticellite intergrowths formed; subsequently pavlovskyite was replaced by dellaite (AM 97.4.503-512).
Pavlovskyite from the Birkhin Gabbro Massif - Image

At Xenolith no. 1, Lakargi Mountain, Upper Chegem volcanic caldera, Chegemsky District, Kabardino-Balkaria, Russia, pavlovskyite was discovered in the altered carbonate xenolith number 3 (sic). The high-temperature rocks in which pavlovskyite was found are skarned carbonate xenoliths. Lakargi Mountain is the type locality of lakargiite, megawite, chegemite, kumtyubeite, calcio-olivine, vorlanite, toturite, irinarassite, bitikleite, elbrusite, magnesioneptunite and rusinovite.
Pavlovskyite was detected as irregular grains in their characteristic skeletal form within cuspidine zones of the skarn with larnite relics. Larnite zones, replaced by cuspidine, toward the contact with slightly altered ignimbrite are transformed to rankinite-wollastonite zones. In these zones pavlovskyite develops on rankinite pseudomorphs after quartz phenocrysts of the ignimbrite. This is especially evident for grains of partially replaced quartz on the boundary between skarn and ignimbrite. Here, pavlovskyite is associated with rusinovite, which also develops after rankinite.
Early high-temperature minerals such as larnite, rankinite, wollastonite, wadalite, rondorfite, kerimasite, tazheranite, baddeleyite, lakargiite, perovskite, apatite and magnesioferrite are preserved in association with pavlovskyite in skarns.
Secondary minerals include trabzonite, killalaite, hydrogarnet, hillebrandite, afwillite, tobermorite-like minerals, jennite, thaumasite-ettringite and hydrocalumite (AM 97.4.503-512).

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