Redmondite

redmondite

hydroredmondite

sulfatoredmondite

thiosulphate

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Formula: [Pb8O2Zn(OH)6](S2O3)4
Thiosulphate (containing [S2O3]2- groups)
Crystal System: Monoclinic
Specific gravity: 5.757 calculated for the empirical formula, 5.680 calculated for the ideal formula
Hardness: 2
Streak: White
Colour: Colourless to shades of brown
Luminescence: No fluorescence under long wave or short wave UV
Solubility: In room-temperature dilute hydrochloric acid, redmondite immediately becomes opaque and then slowly dissolves.
Environments

Metamorphic environments
Hydrothermal environments

Redmondite is a new mineral, approved in 2021 and to date (June 2023) reported only from the type locality

Localities

At the type locality, the Redmond mine, Waterville Lake, Haywood county, North Carolina, USA, redmondite, hydroredmondite and sulfatoredmondite have been found underground. The ore, consisting mainly of galena and sphalerite with lesser amounts of chalcopyrite, occurs in an epithermal (low temperature) vein system consisting of disconnected sulphide-bearing quartz lenses near the contact between a granite gneiss and a mica schist. These redmondite minerals occur in a secondary assemblage that comprises a variety of rare lead-zinc-copper sulphates, thiosulphates and carbonates, including bechererite, chenite, elyite, fassinaite, lahnsteinite, lanarkite, lautenthalite, namuwite, redgillite, osakaite, sidpietersite, steverustite and susannite, as well as some more common secondary minerals such as anglesite, brochantite, caledonite, cerussite, langite, leadhillite, linarite, malachite, posnjakite, schulenbergite and wroewolfeite. Redmondite, hydroredmondite and sulfatoredmondite occur together in vugs in massive galena-sphalerite-chalcopyrite-quartz, in close association with anglesite, cerussite, chenite, elyite, gypsum, lanarkite, steverustite, susannite, and several other potentially new minerals.
The secondary mineral assemblage here is distinguished from any analogous lead-zinc vein known, based on the astonishing diversity of new and/or rare sulphate and thiosulphate minerals found within it. The formation of these rare minerals appears to have been limited to small vugs within the galena-rich ore where exotic metal coordination complexes were stabilised in stagnant solutions under supergene conditions. It appears that at least some thiosulfate precipitation occurred at near-neutral pH conditions in the weathered ore lenses
Redmondite crystals occur as colourless, transparent, equant rhombs up to about 1 mm in size (The Canadian Journal of Mineralogy and Petrology 61.189-202).

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