Dufrénoysite

dufrenoysite

sphalerite

realgar

orpiment

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Formula: Pb2As2S5
Sulpharsenite, sartorite group, forms a series with veenite
Crystal System: Monoclinic
Specific gravity: 5.50 to 5.57 measured, 5.61 calculated
Hardness: 3
Streak: Reddish brown, chocolate brown
Colour: Dark lead-grey, dark red-brown in transmitted light
Environments

Metamorphic environments
Hydrothermal environments

Dufrénoysite is an uncommon mineral of medium to low temperature hydrothermal origin. Associated minerals include chalcopyrite, sphalerite, realgar, orpiment and tetrahedrite (HOM).

Localities

The type locality is the Lengenbach Quarry, Fäld, Binn, Goms, Valais, Switzerland. It has been suggested that the Lengenbach deposit was originally a sulphide-dolomite deposit containing galena and sphalerite, which was invaded by arsenic-rich hydothermal fluids that introduced copper, silver and tellurium in addition to arsenic into the deposit. The lead-arsenic sulphide minerals were formed during metamorphism and hydrothermal alteration with the least arsenic-rich minerals forming first and being progressively replaced by the more arsenic-rich minerals as the reactions progressed. According to this hypothesis, the first lead-arsenic mineral to form at Lengenbach was jordanite, which is not simply structurally related to the sartorite group minerals. Jordanite was followed, in sequence, by dufrénoysite, liveingite, baumhauerite, rathite and sartorite.
It was concluded that two separate paragenetic sequences leading to the formation of the sartorite-group minerals are required to account for the formation of liveingite and rathite.
The flrst sequence is dufrénoysite to liveingite to baumhauerite to sartorite.
The second sequence is dufrénoysite to rathite to sartorite.
The first sequence appears to be dominant at Lengenbach since liveingite, baumhauerite and sartorite are relatively common in the deposit, whereas rathite is very rare. Liveingite has not been found with sartorite, nor baumhauerite with dufrénoysite (AM 75.289-294).

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